Boiling Point Elevation Calculator

Calculate boiling point elevation using ΔTb = i × Kb × m. Supports water, benzene, ethanol, and acetone. Includes altitude correction and van't Hoff factor for ionic solutes.

mol/kg
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ΔTb (Boiling Point Elevation)
New Boiling Point
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mol/kg
°C·kg/mol
°C
ΔTb
New Boiling Point
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g/mol
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°C·kg/mol
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m
ΔTb (Elevation)
Molality
Altitude BP Correction
Corrected Base BP
Final Boiling Point

How to Use This Calculator

  1. Enter the molality of your solution (mol solute per kg solvent).
  2. Select or enter the ebullioscopic constant Kb for your solvent.
  3. Enter the van't Hoff factor i (1 for non-electrolytes, ~1.85 for NaCl).
  4. Optionally enter altitude to correct the base boiling point.

Formula

ΔTb = i × Kb × m

New Boiling Point = BP₀ + ΔTb − (altitude correction)

Altitude correction ≈ −0.34 °C per 100 m elevation

Example

Example: 1 mol NaCl (i = 1.85) in 1 kg water (Kb = 0.512): ΔTb = 1.85 × 0.512 × 1 = 0.947 °C. New boiling point = 100 + 0.947 = 100.95 °C.

Frequently Asked Questions

  • Boiling point elevation is a colligative property: dissolving a solute in a solvent raises the boiling point. The elevation ΔTb = i × Kb × m, where i is the van't Hoff factor, Kb is the ebullioscopic constant, and m is molality.
  • Adding salt slightly raises the boiling point (e.g., 1 tsp salt in 1 L raises BP by only ~0.02 °C). This negligible change does not meaningfully speed up boiling — the main culprit for perception is that salted water actually reaches boiling at a marginally higher temperature.
  • Water's Kb is 0.512 °C·kg/mol. A 1 molal solution of a non-dissociating solute boils at 100.512 °C at sea level.
  • At higher altitudes, lower atmospheric pressure reduces the boiling point by approximately 0.34 °C per 100 m. At 3,000 m (Denver area), water boils around ~90 °C.
  • Both arise from Raoult's Law: solute particles reduce solvent vapor pressure. The solvent must be heated to a higher temperature to overcome the reduced vapor pressure and reach atmospheric pressure.

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Sources & References (5)
  1. Colligative Properties — ACS Chemistry for Life — American Chemical Society
  2. OpenStax Chemistry 2e, Chapter 11: Colligative Properties — OpenStax
  3. IUPAC Compendium of Chemical Terminology — Ebullioscopic Constant — IUPAC
  4. NIST Chemistry WebBook — Fluid Properties — NIST
  5. Atkins' Physical Chemistry, 11th Ed. — Chapter 5: Simple Mixtures — Oxford University Press